New Geochemistry Data for Lake-Bottom Sediments in the Minganie and Basse-Côte-Nord Areas

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2 ew Geochemistry Dt for Lke-Bottom Sedimets i the Migie d Bsse-Côte-ord Ares Eric Hurtubise (CPDM), Srh-Jee Mori (CPDM) d Je-Yves Lbbé (MRF) PRO 29-2 Itroductio The Miistère des Ressources turelles et de l Fue du Québec (MRF), with the coopertio of the Corportio de promotio du développemet miérl de l Côte-ord (CPDM), ouces the publictio of ew geochemistry dt for lke-bottom sedimets i the Migie d BsseCôte-ord res (Figure 1). These dt re ow vilble i SIGEOM, t the followig ddress: qc.c/siget/clsses/i112_idexaccueil?l= uder the tb Geochemistry Sedimet smple. A utility softwre (TrspoSedSIG) tht c be used to covert SIGEOM dt ito esy-to-use tble formt is vilble for our customers. This tool is provided i Access 97 or Access 22 formt t the followig ddress: mies/geology/geology-dtbses.jsp. The geochemistry dt is derived from ew lyses of smples collected i the 198s by the MRF, i three differet regiol surveys. This project is the very first exmple of the type of collbortive effort tht my come out of the specific 3-yer greemet (i effect sice April 1, 28) cocluded betwee the MRF d the Miistère du Développemet écoomique, de l Iovtio et de l Exporttio, the Miistère de l Emploi et de l Solidrité socile, the Miistère des Affires muiciples et des Régios, the Coférece régiole des élus de l Côte-ord, Hydro-Québec, the regiol ACCORD committee, d filly, the CPDM who is the pricipl get. The ultimte gol of this greemet, imed t developig regiol expertise i the cquisitio of secodry eviromet geochemistry dt, s well s promotig d developig the mierl idustry of the Côte-ord regio, is to stimulte ivestmets i mierl explortio i the Côte-ord regio specificlly. Project Descriptio d Methodology of 1 smple per 2.5 km2 (Figure 1). A totl of 11,286 smples were thus re-lyzed withi the scope of this ew project. The re orth of could ot be covered, sice the smples were ot vilble. These smples hve lredy bee re-lyzed, specificlly for titium detectio by QIT, uder greemet with the MRF. Smples were lyzed t AcmeLbs fcilities i Vcouver. A totl of 53 elemets were lyzed by iductively coupled plsm mss spectrometry (ICP-MS) followig qu regi digestio. The results re illustrted o vrious mps provided i this report, which were creted usig the grid optio for the Crete themtic mp fuctio i MpIfo versio 9.5. The mps were geerted usig the iverse distce squred iterpoltio method, bsed o serch rdius of 6 km d squre cells of 3 m x 3 m. For ech elemet, grdes were grouped bsed o percetile rges, mely from to 8, 8 to 9, 9 to 95, 95 to 98, 98 to 99, d 99 to 1. Ares of Iterest The results clerly outlie res of potetil iterest for explortio. Of course, y umber of elemets could hve bee discussed t this time. However, sice the purpose of this publictio is to rpidly relese this ew dt, we chose to illustrte oly the te most sigifict elemets, mely Au, As, Cu, L, Mo, b, i, Pt, Th, d U. The gold mp shows importt omly cetred o the kehm Terre (Figure 2). Two prllel omlies tredig orth-south re clerly visible. This geologicl zoe hs log bee recogized for its polymetllic d gold occurreces. A strog rseic omly is lso preset i this re, slightly offset reltive to the gold omly. The ew dt covers the Migie d Bsse-Côte-ord regiol couty muiciplities (MRC), for totl surfce re of more th 13, km2. The project is bsed o three previous surveys, mely: the Migie survey coducted i 1988, the Bie-Joh-Beetz survey of 1983, d the BsseCôte-ord survey coducted i The geerl smple desity ws of 1 smple per 13 km2, except for the BieJoh-Beetz survey d prt of the Migie survey, where greter mierl potetil wrrted closer smple spcig For i, Cu, d Pt (Figure 3), omly zoes re visible o ech mp, but re ot ecessrily correlted. For i d Cu, omlies re mily cocetrted i the west prt of the mp re, where they re most likely ssocited with mfic rocks i the Lc-à-L Aigle Domi d the Sit-Je Domi. As for Pt, clerly defied omly ppers i the orthwest prt of the mp re. This omly my lso be relted to rocks of the ltter geologicl domis. Editig: Deis L. Lebfevre Trsltio: Michèle Miville Grphic rts: Adré Trembly Dépôt légl Bibliothèque et Archives tioles du Québec, 29 Gouveremet du Québec, 29

3 The urium mp shows extesive omlous domi, from the cetre of the re followig rcute sigture towrd the est (Figure 4). This re correspods to the Mecti orthositic Suite. I the west prt of the mp, other omly is lso visible d coicides with omlies i copper, lthum, d iobium. The ltter my idicte the presece of Fe oxide-type mierliztio. The thorium mp shows o positive correltios with urium, which mkes the urium omlies tht much more iterestig i terms of ore deposit models. I the cse of molybdeum, the results suggest the presece of severl smll omly zoes (Figure 5), some of which re ssocited with urium. I fct, the rcute sigture correspodig to the Mecti orthositic Suite is lso visible o the molybdeum mp. A extesive b omly is clerly visible i the cetre of the mp re (Figure 5). It is probbly ssocited with the west prt of the kehm Terre. I the est prt of the mp, log the Sit Lwrece River, smller omly is visible, ssocited with the Bie-des-Moutos syeite. Filly, for rre erth elemets, which re represeted here by lthum, well-defied omlies re outlied (Figure 5). Some of these pper to be ssocited with urium omlies, while other is correlted with iobium, i the viciity of the Bie-des-Moutos syeite. 5 1 km '' ' '' ' '' ' '' 6 6 ' ' ' '' '' ' ' '' '' '' ' '' ' ) 1927 Boudry by the Privy Coucil (o defiitive ' '' '' ' 12 cblo cblo '' ' '' ' '' ' ' '' Smple 1983 survey - Bie-Joh-Beetz 1988 survey - Migie tshqu tshqu Figure 1 - Loctio mp survey - Bsse-Côte-ord

4 '' '' ' '' 6 ' ' 6 6 '' '' ' 6 ' ' '' '' ' ' ' '' '' '' ' ' '' '' ' ' ' ' '' '' '' '' 1 Km '' '' ' ' '' '' '' ' ' '' ' ' '' '' ' ' '' '' ' '' ' ' i 1927 Boudry by the Privy Coucil (o defiit ' ' '' '' ' '' ' '' ' '' 5 12 blo '' '' ' ' '' '' '' ' '' ' ' ' ' ' '' '' ' '' ' '' 16.9 to percetile 9.6 to percetile 3.1 to percetile 1.8 to percetile 1.2 to percetile <1.2 < 8 percetile Km '' '' ' ' '' '' '' ' '' ' ' ' '' '' '' ' ' '' ' '' '' ' ' '' '' ' '' ' 6 ' 6 6 '' '' ' ' ' ' ' '' '' '' ' '' ' '' ' ' '' '' ' '' ' '' ppb t s h q u i 1927 Boudry by the Privy Coucil (o defiit ' ' '' '' ' '' ' '' ' '' Au c b lo '' '' ' ' '' '' '' ' ' '' ' ' ' '' ' ' '' ' '' '' t s h q u Figure 2 - Mps showig gold d rseic omlies i lke-bottom sedimets. As 7.4 to percetile 4.4 to percetile 2.4 to percetile 1.6 to percetile 1.1 to percetile <1.2 < 8 percetile

5 ' ' ' ' ' ''''''' ' ' ' 6 6 ' '' ' ' ' '' '' '' 5 1 Km ' ' ' ''''''' ' ' ' ' ' '''''' ' ' ' ' ' ' ' ' 1927 Boudry by the Privy Coucil (o defiiti ' ' ' ' '' '' '' '' ' ' '' '' ' ' '' '' ' '' ' '' ' '' 12 c b l o ' ''''' ' ' ' ' ' ' i ' ' '' '' ' '' ' '' ' '' 33.8 to to to to to 18.1 < 14.1 t s hqu ' ' '' '' '' ' ' '' 5 1 Km ' ' ' ' '''' ' ' ' ' ' ' ' ' ' ''''''' ' ' ' ' ' ' 1927 Boudry by the Privy Coucil (o defiiti 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile ' ' ' '' '' '' ' ' ' '' '' '' ' '' ' '' ' ' ' ' ''''''' ' ' ' ' ' ' 6 ' c b l o ' ' ' ''''' ' ' ' ' ' ' ' '' '' '' ' '' ' '' to to to to to 38.9 < ' ' ' '' '' '' ' '' ' '' Km ''''' ' ' ' ' ' ' ' ' ' ' ''''' ' ' ' ' 1927 Boudry by the Privy Coucil (o defiiti 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile t s hqu ' ' ' '' '' '' ' '' ' '' ' ' '' '' ' ' '' '' ' ' '' '' Cu ' ''''''' ' ' ' 6 6 ' ' ' 6 ' ' 6 6 b l o ''''' ' ' ' ' ' ' ' ' ' ' ' ' ' ' '' '' '' Pt ppb 11 to 89 5 to 11 2 to 5 <2 t s hqu Figure 3 - Mps showig ickel, copper, d pltium omlies i lke-bottom sedimets. 99 percetile 98 percetile 95 percetile

6 ' ''''''' ' 6 ' ' ' 6 ' 6 ' ' 6 ' ' ' '' '' '' ' '' ' '' ' ' ' '' '' '' ' '' ' '' 1 Km ' '''' ' ' ' ' ' ' ' ' ' ' ''''''' ' ' ' ' ' i 1927 Boudry by the Privy Coucil (o defiit ' ' '' '' ' '' ' '' ' '' 5 12 blo ' '''''' ' ' ' ' ' ' ' ' ' ' ' '' '' '' 51.5 to to to to to 12.7 < 7. t s h q u Km ' '''' ' ' ' ' ' ' ' ' ' ' ''''''' ' ' ' ' ' ' ''''' ' ' ' 6 6 ' 6 ' ' ' ' 6 6 ' '' ' ' '' '' ' '' ' ' ' '' '' '' '' ' ' '' '' 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile i 1927 Boudry by the Privy Coucil (o defiit ' ' '' '' ' '' ' '' ' '' U b lo '''''' ' ' ' ' ' ' ' ' ' ' ' ' '' '' '' t s h q u Figure 4 - Mps showig urium d thorium omlies i lke-bottom sedimets. Th 15.3 à à à à à 5. < percetile 98 percetile 95 percetile 9 percetile 8 percetile

7 '' '' ' ' '' '' ' ' '' 6 6 ' ' ' ' '' '' ' '' ' '' '' 5 1 Km '' '' ' ' '' '' '' ' ' ' '' ' 1927 Boudry by the Privy Coucil (o defiiti ' ' '' '' ' ' ' ' '' '' '' '' ' ' ' '' '' '' ' '' ' '' ' '' '' '' '' ' ' '' '' ' ' '' ' ' 12 c b l o '' '' '' ' ' ' '' '' ' ' '' ' Mo ' ' '' '' ' '' ' ' '' '' ' '' to to to to to 6.47 < 3.97 ' ' ' '' '' '' ' '' ' '' 5 1 Km '' '' ' ' '' '' '' ' ' '' ' ' 1927 Boudry by the Privy Coucil (o defiiti 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile t s hqu ' ' '' '' ' '' ' ' '' '' ' ' ' ' '' '' '' '' ' ' '' '' '' '' ' ' '' '' '' ' ' ' '' ' '' ' ' '' '' ' '' ' ' 12 c b l o '' ' '' ' '' '' ' ' ' '' ' '' '' ' ' '' ' '' 7.95 to to to to to 4.47 < Km '' '' ' ' '' '' '' ' ' '' ' '' '' ' ' '' '' ' '' ' ' 6 6 ' 6 ' ' ' '' '' '' ' '' ' '' ' ' ' '' '' '' ' ' ' '' '' 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile t s hqu 1927 Boudry by the Privy Coucil (o defiiti ' '' ' ' '' '' ' '' b '' '' ' ' '' '' ' ' '' ' bl o '' ' '' ' '' ' '' ' ' '' ' ' '' '' '' ' ' '' ' '' t s hqu L to to to to to < 82.2 Figure 5 - Mps showig molybdeum, iobium, d lthum omlies i lke-bottom sedimets. 99 percetile 98 percetile 95 percetile 9 percetile 8 percetile

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