POPs - inventarizácia emisií
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1 POPs - inventarizácia emisií Slovak Hydrometeorological Institute Jana Matejovičová
2 POPs definícia * Persistentné organické látky (POPs) : Majú toxické vlastnosti; Sú persistentné; bioakumulujú; (rozpustné v tukoch) Sú chopné prenosu na veľké vzdialenosti; Pravdepodobne zapríčiňuju závažné poškodenie ľudského zdravia a životného prostredia * Protokol o perzistentných organických látkach k Dohovoru EHK OSN o diaľkovom znečisťovaní ovzdušia prechádzajúcom hranicami štátov -CLRTAP
3 Vznik POPs Neúmyslená produkcia ( by-products všetky reportované POPs) úniky (PCB zo starých transformátorov a kondenzátorov) Medziprodukt (HCB v chemickom priemysle) Prirodzený pôvod Nehody V niektorých krajinách je použitie niektorých POPs povolené (DDT malária,...)
4 Transport and depozícia POPs V plynnom stave (POPs are semivolatile substances) Adsorbované na prachových časticiach Resuspenzia z pôdy a sedimentov
5 Medzinárodné dohovory o POPs Protokol o perzistentných organických látkach k Dohovoru EHK OSN o diaľkovom znečisťovaní ovzdušia prechádzajúcom hranicami štátov -CLRTAP (Aarhuský protokol, 1998 do platnosti vstúpil 23. októbra 2003) Štokholmský dohovor o perzistentných organických látkach (Stockholm Convention on Persistent Organic Pollutants) (Slovensko ratifikovalo , dohovor vstúpil do platnosti ) Bazilejský dohovor o riadení pohybov nebezpečných odpadov cez hranice štátov a ich zneškodňovaní, 1989 Rotterdamský dohovor o nebezpečných chemických látkach a pesticídoch v medzinárodnom obchode (Rotterdam Convention on Harmfull Chemicals and Pesticides, 1998)
6 Porovnanie Aarhuského protokolu a Štokholmského dohovoru Substance Polychlorinated dibenzodioxines and dibenzofurenes (PCDD/F) Protocol to the CLRTAP on POPs x Stokholm Convention x Polychlorinated biphenyls (PCB) x x Hexaclorobenzene (HCB) x x Polyaromatic hydrocarbons (PAH) Others - POPs Pesticides: Aldrin, Chlordane, Chlordecone, Dieldrin, Endrin, Heptachlor, Hexabromobiphenyl*, Mirex, Toxaphene, Hexachlorocyclohexane x x x** *fire retardant, **the same substances as Protocol, excepted: Chlordecone, Hexachlorocyclohexane (lindan), Hexabromobiphenyl
7 Štokholmský dohovor nové látky (návrh) Pentabromodiphenyl ether (proposed by Norway) Chlordecone (proposed by the European Communities and the Member States that are Parties to the Convention) Hexabromobiphenyl (proposed by the European Communities and the Member States that are Parties to the Convention) Lindane (proposed by Mexico) Perfluorooctane sulfonate (PFOS) (proposed by Sweden) Pentachlorbenzene (EC, draft of proposal) Octabromodiphenyl ether (EC, draft of proposal) Short-chained chlorinated paraffins (EC, draft of proposal)
8 Legislatíva na úrovni Komisie s opatreniami súvisiacimi s POPs I nariadenie (ES) č. 850/2004 Európskeho parlamentu a Rady o perzistentných organických látkach a o zmene smernice 79/117/EHS smernica 79/117/EHS týkajúcej sa zákazu uvádzania na trh a používania prípravkov na ochranu rastlín obsahujúcich určité účinné látky v aktuálnom znení nariadenie (ES) č. 304/2003 Európskeho parlamentu a Rady o vývoze a dovoze nebezpečných chemikálií smernica Rady 96/59/ES o zneškodňovaní PCB/PCT smernica Rady 67/548/EHS o aproximácii zákonov, nariadení a administratívnych opatrení vo vzťahu ku klasifikácii, baleniu a označovaniu nebezpečných látok v aktuálnom znení, smernica Rady 91/414/ES týkajúca sa umiestnenia prostriedkov na ochranu rastlín na trh. smernica EP a Rady 98/8/ES o biocídnych prostriedkoch smernica Rady 96/61/ES o IPKZ rozhodnutie komisie 2000/479/ES vzťahujúce sa na EPER návrh COM(2004)634 final vzťahujúce sa na PRTR rámcová smernica Rady 75/442/ES o odpade
9 Legislatíva na úrovni Komisie s opatreniami súvisiacimi s POPs II smernica Rady 91/689/EHS o nebezpečnom odpade smernica Rady 75/439/ES o zneškodňovaní odpadových olejov smernica EP a Rady 2002/96/ES o elektronickom šrote v aktuálnom znení smernica 2000/53/ES o starých vozidlách smernica 2000/76/ES o spaľovaní odpadov smernica 2002/80/ES o veľkých spaľovacích zariadeniach smernica EP a Rady 2004/107/ES o As, Cd, Hg, Ni a PAH v ovzduší smernica SEVESO II 96/82/ES o kontrole významných havárií smernica 76/464/EHS o znečistení zapríčinenom určitými nebezpečnými látkami smernice Rady 1988/347/EHS o emisiách niektorých POPs smernica Rady 1988/280/EHS o DDT smernica Rady 1984/491/EHS o HCH rámcová smernica o vode 2000/464/ES nariadenie Rady (EHS) o kontrole a riadení pohybu odpadov v, cez a do Spoločenstva
10 Inventarizácia emisií - metodika PCDD/F - Standardized Toolkit for Identification and Quantification of Dioxin and Furan Releases, UNEP Chemicals, February 2005 Ostatné látky národné metodiky (merania v Poľsku a ČR) EMEP/CORINAIR Emission Inventory Guidebook, January 2004
11 PCDD/F
12 PCB
13 HCB Výroba železných a neželezných kovov 18% Výroba minerálnych produktov 2% Ostatné 1% Spaľovne odpadov 34% Výroba energie, tepla, temické procesy 45%
14 PAH (benzo(a)pyrén, benzo(b)fluorantén, benzo(k)fluorantén, indeno(1,2,3-cd)pyrén) Výroba energie, tepla, temické procesy 77% Ostatné 4% Doprava 1% Nekontrolované spaľovacie procesy 1% Výroba železných a neželezných kovov 17%
15 PAH rekalkulacia
16 Projekty PHARE Počiatočná pomoc Slovenskej republike pri plnení záväzkov vyplývajúcich zo Štokholmského dohovoru o perzistentných organických látkach >NIP Emisie PCDD/F v kandidátskych krajinách -> merania, inv.
17 BaP - počiatky monitoringu odberu B(a)P zo vzorky ovzdušia, extrakcie tohto analytu zo sorpčnej sústavy (odberového filtra), čistenia získaného extraktu stanovenia B(a)P v prečistenom zakoncentrovanom extrakte metódou GC/MSD.
18
19 Zhrnutie Emisie: Upresňovať EF pre inventarizáciu POPs zvlášť pre malé zdroje Upresňovať informáciu o vstupoch Cesta - spolupráca s ČR a Poľskom Monitoring Pasívne meranie spolupráca s RECETOX GC/MSD?
20 Ďakujem za pozornosť
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