Linker Original Linker Name L1 BTT = 1,3,5- benzenetristetrazolate L2 (HETT = 5,5,10,10,15,15 - Hexaethayltruxene- 2,7,12- MOF Original MOF Name Parent Metal Exchanged Metal Additional Notes Ref. 1 Mn 3[(Mn4Cl)3(BTT)8(CH3OH)10] Mn 2+ - 31 1 Cu (I) - Cu + Near negligible exchange 1 Li Li3.2Mn1.4[(Mn4Cl)3(BTT)8]2 0.4 LiCl Li + Little exchange 1 Co Co3[(Mn4Cl)3(BTT)8]2 1.7CoCl2 Co 2+ Guest cations exchanged only 1 Fe Fe3[(Mn4Cl)3(BTT)8]2 FeCl2 Fe 2+ Guest cations exchanged only 1 Ni Ni2.75Mn0.25[(Mn4Cl)3(BTT)8]2 Ni 2+ Guest cations exchanged only 1 Cu Cu3[(Cu2.9Mn1.1Cl)3(BTT)8]2 2 (II) CuCl2 1 Zn Zn3[(Zn0.7Mn3.3Cl)3(BTT)8]2 2Z ncl2 2 Cd 1.5(H3O)3[(Cd4O)3(HETT)8] 6H2O 2 Pb Pb(H3O)[<Pb4(µ4O)>3(HETT)8] 6H2O Cu 2+ Partial node exchange Zn 2+ Partial node exchange Cd 2+ 50 Pb 2+ Complete exchange 2 days Partial reverse exchange possible L3 -OOCClH 3C6Fc 3 [Zn(OOCClH3C6Fc)2(H2O)3]n Zn2+ 25 Cd 2+ 18% exchange max. Pb 2+ 26% exchange max. 4 ([Zn(bpy)2(FcphSO3)2]n Zn2+ 22 L6 FcphSO 3 - Pb 2+ Metal sorption only at low conc. of exchange solution Cd 2+ Cu 2+ L5 Bpp=1,3-bis(pyridine- 5 <[Cd(bpp) 2(O3SFcSO3)](CH3O Cd 2+ 48
4-yl)propane H) 2>n L7 O 3SFcSO3 6 <[Cd(bpy)2(O3SFcSO3)](CH3O H)4>n L7 O3SFcSO3 L8 N-phenyl-N -phenyl bicyclo[2,2,2]oct-7- ene-2,3,5,6- tetracarboxydiimide tetracarboxylic acid L10 bis(1h-1,2,3-triazolo- [4,5-b],[4`,5`i])dibenzo-[1,4]-dioxin 7 [Zn7(L1)3(H2O)7]n [Zn5(L8)3(H2 O)5]n Pb 2+ Metal sorption only at low conc. of exchange solution Cu 2+ Cd 2+ 48 Pb 2+ Metal sorption only at low conc. of exchange solution Cu 2+ Zn 2+ 53 7 Cu Cu 2+ 87% exchange 8 MOF-5 [Zn4O(BDC)3] Zn2+ 24 Ni 2+ 25% nickel exchange per node 9 MFU-4l Zn2+ 23 Co 2+ Replaces only tetrahedral Zn, as opposed to octahedral 10 Al-MIL-53 Al 3+ 54 Fe 3+ Particle to particle exchange 10 Fe-MIL-53 Fe 3+ 54 Al 3+ Particle to particle exchange 11 UiO-66 Zr 4+ 54
L12 1,2,3-tris(3,5- dicarboxylphenylethyn yl)benzene Ti 4+ 38% exchange Hf 4+ 20% replacement 12 Zn 3(BTB)2(H2O)2 Zn2+ 47 Cu 2+ Partial exchange 13 PMOF-2 [Zn24L128(H2O)12] Zn 2+ 47 Cu 2+ Full exchange 14 Zn6(BTB)4(Bpy)3 Zn 2+ 8 Cu 2+ Core/shell exchange Co 2+ Core/shell exchange (reversible) Ni 2+ Core/shell exchange 15 Cu 6(BTB)4(Bpy)3 Cu2+ 8 Zn 2+ No exchange Co 2+ No exchange Ni 2+ No exchange 16 Co 6(BTB)4(Bpy)3 Co2+ 8 Zn 2+ Core/shell exchage (reversible) Cu 2+ Core/shell exchange Ni 2+ Core/shell exchange 17 Zn 6(BTB)4(Bpy)3 Ni2+ 8 Zn 2+ No exchange
L12 N,N -bis(3,5- dicarboxyphenyl)pyro mellitic diimide L12 N,N -bis(3,5- dicarboxyphenyl)pyro mellitic diimide L13 benzene-1,3,5- triyltriisonicotinate. L13 benzene-1,3,5- triyltriisonicotinate. L14 BTX = 1,4-bis(triazol- 1-ylmethyl)benzene 18 <[Zn 2(BDCPPI)(DMF)3] 6 DM F 4H2O>n, or, SNU-51 Cu 2+ Core/shell exchange Co 2+ No exchange Zn 2+ 28 19 <[Zn2(BDCPPI)(DMF)3] 6 DM F 4H2O>n, or, SNU-51 Cu 2+ Exchange is irreversible, and solvent dependent, and preferential for Cu 2+ over Cd 2+, Co 2+, Ni 2+ Cu 2+ 28 20 Zn6(BTB)4(Bpy)3](Sol)x or SUMOF-1-Zn, Sol = solvent Zn 2+ 29 20 C u 20 C o Cu 2+ 50% exchange in 1 hour, 99% after 3 months, reverse exchange only proceeds to 38% Co 2+ 35% exchange, reversible 20 Ni Ni 2+ 38% exchange, reversible 21 Zn <Zn(L13)2(H2O)2] 2(PF6) pyre Zn 2+ 56 ne 2(H2O)>n 21 C d 22 C d <[Cd(L14)2(H2O)2] 2(PF6) pyr ene 2(H2O)>n Cu 2+ Complete exchange, 6 hours, irreversible Cd 2+ 56 Cu 2+ Complete exchange, 8 hours, reversible to 53% <[Cd2(BTX)2(BDC)2] H2O> Cd2+ 30
L14 BTX = 1,4-bis(triazol- 1-ylmethyl)benzene L15 4,4,4,4 -ethene- 1,1,2,2-tetrayltetrakis ([1,1 -biphenyl]-3,5- ) (H8ETTB) L16 (R,R)-( )-1,2- cyclohexanediamino- N,N -bis(3- tert-butyl- 5-(4- pyridyl)salicylidene)m n III Cl L17 tetrakis(4- carboxyphenyl)- benzene 22 C o Cu 2+ Complete exchange, 1 week <[Co2(BTX)2(BDC)2] H2O> Co2+ 30 23 PCN-921 Zn 4 (ETTB) 4DMF xs Cd 2+ Complete exchange, 1 week Zn 2+ 57 23 C u PCN-922, Cu 4 (ETTB) 4DMF xs 24 Mn 3+ : salens Zn 2+ : nodes Cu 2+ Complete exchange, 4 days 15 Co 2+ metalated salen after Mn 3+ Zn 2+ metalated salen after Mn 3+ Mn 2+ metalated salen after Mn 3+ Ni 2+ metalated salen after Mn 3+ Cr 2+ metalated salen after Mn 3+
L18 TMPyP = meso- tetra(n-methyl-4- pyridyl)porphyrine L19 Bpt = biphenyl L18 TMPyP = meso- tetra(n-methyl-4- pyridyl)porphyrine L19 Bpt = biphenyl L20 tetracarboxyphenylpor phyrin H4-TCPP-H2 = (C48H24O8N4). 25 Cd 6(BPT)4Cl4(H2O)4], porph@mom-10 Cd 2+ : nodes and porphy rines Cu 2+ Partial exchange in nodes and metalated salen 25 Mn Mn-porph@MOM-10 Mn 2+ Full exchange in nodes and porphyrines, 1 week 25 C u Cu4Cd2(BPT)4Cl4(CH3OH)4] [C 44H36N8Cu, Cuporph@MOM- 10-CdCu Cu 2+ Partial exchange in nodes and porphyrines 26 porph@mom-11 Cd 2+ 11 26 Ba porph(cl - )@MOM-11(Ba 2+ ), [Cd4Ba0.5(BPT)4(Solvent)3] [Cd(C44H36N8)(Cl)] [Solvent] 26 N a porph(cl - )@MOM-11(Na + ) ([Cd4Na(BPT)4(Solvent)3] [Cd(C44H36N8)(Cl)] [Solvent] 26 Mn porph(cl - )@MOM-11(Mn 2+ ) [Cd8Mn(BPT)8(Solvent)4] 2[Cd(C44H36N8)(Cl)] [Solvent] 27 (Zr 6O4(OH)4(TCPP-H2)3, MOF- 525 Ba 2+ Sorption to metal nodes Na + Sorption to metal nodes Mn 2+ Partial node exchange Zr 4+ 63 Cu 2+ Full porphyrin metalation L20 tetracarboxyphenylpor 28 MOF-545, Zr 4+ 63 10
phyrin H4-TCPP-H2 = (C48H24O8N4). [(Zr6O8(H2O)8(TCPP-H2)2] Cu 2+ Full porphyrin metalation Fe 2+ Full porphyrin metalation