PM Measurements at the Port of Patras

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POSEIDON Pollution monitoring of ship emissions: an integrated approach for harbours of the Adriatic basin Priority 2: Environmental Protection Topic 1: Sources of land-based and sea-based pollution Deliverable 2.4 (Annex) PM Measurements at the Port of Patras Partner P3 Laboratory of Atmospheric Physics University of Patras June 2015 1

Working group: Prof. Athanassios Argiriou (Laboratory of Atmospheric Physics, University of Patras) M.Sc. Vasileios Salamalikis (Laboratory of Atmospheric Physics, University of Patras) M.Sc. Constantinos Katsidimas (Department of Physics, University of Patras) 2

CONTENTS 1. INTRODUCTION... 4 2. OVERVIEW OF THE MEASUREMENTS... 5 2.1. Monthly values... 5 2.2. Raw 10 minutes data series... 7 2.3. Daily data series... 8 Acknowledgements... 13 3

1. INTRODUCTION In the frame of the POSEIDON Project, the Laboratory of Atmospheric Physics of the University of Patras performed continuous monitoring of PM measurements at the area of the new (south) port of Patras. The measurements had started on October 2013, in the frame of the CESAPO project (ETCP Greece Italy, 2007 2013) (www.cesapo.upatras.gr) and continued in the frame of POSEIDON. Measurements were performed using the Environmental Dust Monitor #180 of Grimm Technologies Inc, that belongs to the Environment Laboratory of the School of Natural Sciences of the University of Patras. The location of the monitoring equipment is shown in Figure 1.1. Figure 1.1. PM monitoring equipment at the south Port of Patras (photos: courtesy Ing. Spyros Crotsis) The monitoring equipment measures continuously the concentrations of PM 10, PM 2,5, PM 1 (in µg.m -3 ). The sampling air flow is set at 1.2 L.min -1. Measurements are stored as ten-minute averages; a database with the measurements is available. The following report provides a short overview of the complete time series. Monitoring started on and is ongoing. There is a gap starting March 11th, 2015, 10:24:00 UTC until April 8th, 2015, 11:13:00 UTC. During this period the sampler had to be shipped to Athens for the regular maintenance and recalibration. 4

2. OVERVIEW OF THE MEASUREMENTS 2.1. Monthly values The monthly values are reported in Table 2.1 and shown graphically in Figure 2.1 Table 1. Monthly average and maximum concentrations of PM 10, PM 2,5, PM 1. Date PM 1.0 (μg/m 3 ) PM 2.5 (μg/m 3 ) PM 10 (μg/m 3 ) PM 1.0 PM 2.5 PM 10 (μg/m 3 ) (μg/m 3 ) (μg/m 3 ) Mean Max Oct 2013 16,15 20,89 36,65 63,7 69,5 207,5 Nov 2013 17,24 21,14 33,28 197,4 201,5 208,6 Dec 2013 48,22 52,06 66,51 290 305 344 Jan 2014 37,10 41,93 58,23 252,9 259,9 389,4 Feb 2014 26,36 30,30 42,86 223,4 236,4 550,1 Mar 2014 22,31 25,88 38,74 160,2 164,8 331,6 Apr 2014 12,02 17,21 30,03 68,9 147,9 559 May 2014 9,86 14,31 26,48 190,6 240,4 647,5 Jun 2014 12,62 18,11 36,48 35,9 117,2 991,6 Jul 2014 9,39 13,03 25,62 37,3 90,2 690,1 Aug 2014 9,93 13,99 29,83 49,3 315,4 1740,8 Sep 2014 9,23 12,76 22,35 62,6 76,3 186,3 Oct 2014 11,93 16,04 28,88 59,1 61,4 140 Nov 2014 29,15 34,64 49,93 176,1 184 225 Dec 2014 32,08 36,15 48,04 180 188,2 231,1 Jan 2015 31,77 36,26 47,75 178,6 185,1 301,4 Feb 2015 21,42 29,48 48,59 160,4 382 1203,2 Mar 2015 16,65 19,03 25,62 96,5 105,6 143,2 Apr 2015 15,69 19,21 31,18 74,2 78,3 125,5 May 2015 10,61 14,02 28,01 62,9 79,7 780,5 5

Figure 2.1. Monthly average (a) and maximum (b) concentrations of PM 10, PM 2,5, PM 1 for the complete monitoring period. 6

2.2. Raw 10 minutes data series Figure 2.2. Raw 10-minute values, as stored by the monitoring equipment for (a) PM 1, (b) PM 2,5 and (c) PM 10. The data gap at the end of the time series corresponds to the maintenance calibration period of the instrumentation. 7

2.3. Daily data series Figure 2.3. (a) mean, (b) daily minimum, (c) maximum and (d) abs(maximum-minimum) PM 1 values. 8

B) PM 2.5 Figure 2.4. (a) mean, (b) daily minimum, (c) maximum and (d) abs(maximum-minimum) PM 2.5 values. 9

Figure 2.5. (a) mean, (b) daily minimum, (c) maximum and (d) abs(maximum-minimum) PM 10 values. 10

Figure 2.6. Daily average values as a function of the day of the year. Black dots correspond to the year 2013, red dots to the year 2014 and blue dots to the year 2015. 11

Figure 2.7. Daily minimum values as a function of the day of the year. Black dots correspond to the year 2013, red dots to the year 2014 and blue dots to the year 2015. 12

Figure 2.8. Daily maximum values as a function of the day of the year. Black dots correspond to the year 2013, red dots to the year 2014 and blue dots to the year 2015. Acknowledgements The Laboratory of Atmospheric Physics of the University of Patras acknowledges the contribution of the Port Authority of Patras for allowing the installation of the monitoring equipment at its premises and for providing the necessary infrastructure for its smooth and safe operation. The help of Professor Constantinos Platycostas, President and Managing Director of the Patas Port Authority, Mr. Stavros Antypas Mr. Photios Smyrnis and Mr. Dimitrios Koletsos, is greatly acknowledged. 13