Short Cruise Report Schiff und Fahrt - Nr. MSM 79-2

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Stefan Kinne MPI-Meteorologie Bundesstrasse 53 20146 Hanburg Germany Tel.: 040 41173 383 Fax: 040 41173 298 email: Stefan.Kinne@mpimet.mpg.de Short Cruise Report Schiff und Fahrt - Nr. MSM 79-2 Mindelo (Kapverden) - Bahia de las Minas (Panama) 6. Dez 2018-18. Dez 2018 Chief Scientist: Stefan Kinne Captain: Björn Maaß The MSM 79-2 route until December15 (red line) on the research cruise from Mindelo (Capo Verde) to Panama. Also indicated are the deployment locations of the six ARGO floats (black dots).

Objectives As the title MOOR (Measuring Over Ocean References of aerosol, clouds and tracegases for evaluations of satellite retrievals and model simulations) indicates, the major focus of the MSM 79-2 research cruise was the sampling of atmospheric reference data. Three sun-photometers (for aerosol) and two MAX-DOAS instruments (for trace-gases) were brought along in personal luggage and quasi permanent installed ceilometer and cameras (for clouds) were already installed or onboard. In addition, the cruise opportunity was used (1) to deploy 6 ARGO floats and (2) to analyze the underway sampling of ocean surface properties (temperature and sea-salt content with a thermosalinograph), ocean currents (in two different altitude regimes with two vessel-mounted VM-ADCPs Ocean Surveyors) and bathymetric sampling of the oceans floor (depth and composition with the Kongsberg EM122 multi-beam echo sounder data).

Narrative The MSM 79-2 cruise started on December 6 with a slight delay as part of the crew and some luggage were stuck in Lissabon. Late in the afternoon of December 6 the Merian departed from Mindelo. Due to electrical issues only one pot could be used to propel the ship. This limited the speed to about 9 knots, as speed far to slow to reach Panama in time. We had, however, a technician onboard and were hopeful that the problem could be fixed. We had received a science permit for Cape Verde so we could start sampling soon after leaving Mindelo. All atmospheric instruments (sun-photometers, cloud cameras, ceilometer and MAX-DOAS instruments) worked as planned and even an old cloud camera, stored in the basement of the ship was brought onto the piledeck and activated. As soon as we left the Capo Verde EEZ the first of the six ARGO floats was deployed. As the forward speed remained slow the planned CTD profile at the deployment location had to be scratched out of time-concerns. Although after about three days we went back to full speed (at 13kn) the captain still signaled concerns about future propulsion problems so all CTD profiles needed to be scratched (In hindsight this was unfortunate as the propulsion system turned out to be OK and there was plenty of help from ocean currents and easterly winds so in the end we were even slightly ahead of schedule). With relatively few clouds present we could sample many reference data for aerosol and clouds, but for trace-gases we were limited to a few good samples early on, when wind speeds were still low. When the easterly (trade) winds at the surface picked up (for the rest of the cruise >10m/2) after a few days, the winds were faster than the ship s forward movement even at full speed. AS a result the motor exhaust was pushed over both MAX-DOAS instruments (in the front of the ship) and their oceanic background data were frequently contaminated. Thus, on two days (december 12 and 13) the ship was turned for ca 20 minutes into a southern (then perpendicular to the wind) direction to allow for at least a few good background data at the TROPOMI satellite overpass near 13.30 local time. Shortly before we reached the Barbados EEZ, we finally received clearance to sample in Barbados waters. Thus, we performed a desired manoever at the east coast of Barbados, where the MPI-M maintains a cloud observing station since 2010 (the BCO site). With identical cloud instruments (ceilometer and thermal camera) as on the ship we approached that site in direction of cloud base (ca 940hPa) movement from 50 miles out to as close as 1 mile (almost at midnight). After another half hour forth and back in and out the wind-direction we passed Barbados Island to the north. Once we left the Barbados EEZ, we has to stop our scientific work, as we did not have permits for countries like Venezuela or Columbia, which are difficult to obtain, also as time between cruise approval (in August) and cruise (in December) was too short. Some figures below summarize initial results for the Atlantic cross-section betwee -60W and -25W near 15N in December: Figure A: Sea surface salinity gained by the thermosalinograph on cruise MSM79-2. (UNI-HH) Figure B: Sea surface temperature gained by the thermosalinograph on cruise MSM 79-2. (UNI-HH) Figure C Atlantic cross-sections for December at 15N between -60W and -25 W for temperature, relative humidity and wind-speed at the surface and for broadband solar and infrared radiation. (MPI-M) Figure D Atlantic cross-sections for December at 15N between -60W and -25 W for sun-photometer derived data for AOD at 550nm, Angstrom parameter, aerosol index and water vapor. (MPI-M) Figure E NO2 column data sampled along the Atlantic cross section. The occasional higher values on the western side are caused by sampling ship exhaust (due to unfavorable winds). (MPI-C) Figure F mid-visible sunphotomter optical depth measurement summary (left) and NO2 loads at different elevations (15,30 deg) above the horizon (right) with larger pollution early on after leaving Mindelo. (KNMI) Figure G ocean floor details for the Atlantic Ridge and near Capo Verde. (HCU)

Figure A: Sea surface salinity gained by the thermosalinograph on cruise MSM79-2. (UNI-HH) Figure B: Sea surface temperature gained by the thermosalinograph on cruise MSM 79-2. (UNI-HH) Figure C Atlantic cross-sections for December at 15N between -60W and -25 W for temperature, relative humidity and wind-speed at the surface and for broadband solar and infrared radiation. (MPI-M)

Figure D Atlantic cross-sections for December at 15N between -60W and -25 W for sun-photometer derived data for AOD at 550nm, Angstrom parameter, aerosol index and water vapor. (MPI-M) Figure E NO2 column data sampled along the Atlantic cross section. The occasional higher values on the western side are caused by sampling ship exhaust (due to unfavorable winds). (MPI-C)

Figure F mid-visible sunphotomter optical depth measurement summary (left) and NO2 loads at different elevations (15,30 deg) above the horizon (right) with larger pollution early on after leaving Mindelo. (KNMI) Figure G ocean floor details for the Atlantic Ridge and near Capo Verde. (HCU) Acknowledgements We thank the crew for the relaxed home away from home atmosphere, the captain for helping in achieving our science goals, with route changes even on short notice, the kitchen for the excellent food, and the Leitstelle Deutsche Forschungsschiffe in Hamburg for their assist in getting the permission for sampling in Barbados EEZ in the last minute.

Teilnehmerliste 1. Stefan Kinne Fahrtleiter / Chief Scientist MPI-M 2. Ulrike Kirchner Sonnenphotometer (Aerosole) MPI-M 3. Stephanie Fiedler Kameras (Wolken) MPI-M 4. Olaf Tuinder MAX-DOAS (Spurengase) KNMI 5. Vinod Kumar MAX-DOAS (Spurengase) MPI-C 6. Dagmar Hainbucher Thermosalinograph, CTD UNI-HH 7. Anja Schneehorst ARGO floats BSH 8. Melanie Steffen bathymetry HCU 9. Mila Schopenhauer bathymetry HCU MPI-M Max-Planck Institute für Meteorologie Hamburg KNMI Koninklijk Nederlands Meteorologisch Instituut De Bilt MPI-C Max-Planck Institute für Chemie Mainz BSH Bundesamt für Seeschifffahrt und Hydrographie Hamburg UNI-HH Universität Hamburg, Meereskunde Hamburg HCU Hafen City Universität Hamburg list of stations - no stations - 6 ARGO floats deployed Table Details to the ARGO float deployments Float S/N WMO Lat Lon DeplDate [UTC] 8593 3901677 14 37,570' N 047 59,812' W 2018-12-11 21:36:28 8594 3901676 15 29,154' N 039 00,122' W 2018-12-10 03:00:58 8595 3901684 15 45,825' N 035 59,923' W 2018-12-09 10:24:37 8596 3901683 16 02,796' N 032 59,857' W 2018-12-08 16:52:32 8597 3901682 16 17,992' N 030 00,014' W 2018-12-07 23:10:05 8598 3901681 16 26,289' N 028 47,514' W 2018-12-07 16:00:55