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1 Revision date: Page 1/7 1. IDENTIFICATION OF THE MIXTURE AND COMPANY. UNDERTAKING Product name:: Product characteristic : Two-components, structural, methacrylic adhesive (base) Application: To structural bonding of thermoplastic, metal and composite assemblies. Distributor: PROXIMA NTR Sp. z o.o. ul. Piłsudskiego Bełchatów Telephone no.: Fax no: Alarm telephone no (working hours ) address: ntr@ntr.com.pl 2. HAZARDS IDENTIFICATION Classification: C Corrosive F Highly flammable Contains:: Methacrylic acid, methyl methacrylate, Risk phrases: R34 R43 R36/37/38 Causes burns May cause sensitization by skin contact Issitating to eyes, to respiratory system and skin 3. COMPOSITION / INFORMATION ON INGREDIENTS Name Index No. CAS No. EC No. Classification Content Methacrylic acid C, R35, Xn, R21/22 1 < x <10 Methyl methacrylate F, R11, R43, Xi, R37/38 30 < x < FIRST AID MEASURES General information: Inhalation: Ingestion: Skin contact: Eye contact: Do not breathe vapour/spray. Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately(show label where possible). Move the exposed person to fresh air at once. Contact physician if discomfort continues. Do not induce vomiting. Drink plenty of water. Get medical attention. Remove affected person form source of contamination. Wash skin thoroughly with soap and water for several minutes. Contact physician if irritation persists. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 5. FIRE-FIGHTING MEASURES Extinguishing media: Special fire fighting procedures: Extinguishing with foam, carbon dioxide or dry powder. Keep up-wind to avoid fumes. Avoid water in straight hose
2 Issuance date: Revision date: Page 2/7 Specific hazards: Protective measures in fire: stream;will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Highly flammable. Avoid breathing fire vapours. May travel considerable distance to source of ignition and flash back. Polymerises generating heat. Self contaminated breathing apparatus and full protective clothing must be worn in case of fire. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Warn everybody of potential hazards and evacuate if necessary. Remove source of ignition. Avoid inhalation of spray mist and contact with skin and eyes. Wear protective clothing as described in Section * of this safety data sheet. Provide adequate ventilation. Environmental precautions: Do not allow to enter drains, sewers or watercourses. Spillages or uncontrolled discharges into watercourses must be immediately alerted to the Environmental Agency or other appropriate regulatory body Spill clean up method: Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. 7. HANDLING AND STORAGE Usage precautions: Storage precautions: Use only in well-ventilated areas. Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit is not exceeded. Do not breathe vapour. Avoid contact with skin and eyes. Take precautionary measures against static discharge. Storage tanks and other containers must be grounded. Do not smoke, use naked flames or other sources of ignition. Do not eat, drink or smoke when using the product. Observe good industrial hygiene practices. Store in tightly closed original container in a cool, dry well-ventilated place. Keep away from heat, sparks and open flame. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std LT-ppm LT- mg/m 3 ST ppm ST - mg/m 3 Methyl methacrylate WEL Methacrylic acid WEL Name NDS NDSCh Methyl methacrylate 50 mg/m³ 400 mg/m³ Process conditions: Engineering measures: Respiratory equipment: Provide eyewash, quick drench Provide adequate general and local exhaust ventilation If ventilation is insufficient, suitable respiratory protection must provided.
3 Revision date: Page 3/7 Hand protection Eye protection: Hygiene measures: Skin protection Use protective gloves made of rubber or plastic. Wear approved chemical safety goggles where eye exposure is reasonably probable. Keep away from food, drink and animal feeding stuffs. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Do not drink, eat or smoke when using the product. Change work clothing daily before leaving work place. Wear apron or protective clothing in case of contact. National regulations: Rozporządzenie Ministra Pracy i Polityki Społecznej z dn. 29 listopada 2002 r. w sprawie najwyższych dopuszczalnych stężeń i natężeń czynników szkodliwych dla zdrowia w środowisku pracy (Dz. U. Nr 217, poz. 1833) z późniejszymi zmianami. 9. PHYSICAL-CHEMICAL PROPERTIES Appearance Odour Colour ph Parameters Value Paste Slightly pungent odour White / off-white < 7 ;20 o C Boiling point 101 C Melting point - 47,7 C Flash point 10 C Flammability limit-lower % 1,7 Flammability limit- upper % 12,5 Relative density Viscosity 0,96 (20 C) mpa*s Evaporation rate 3 (butyl acetate = 1) Vapour pressure 28 mmhg ( 20 C) 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Hazardous polymerisation: Materials to avoid: Hazardous decomposition products: May polymerise Heating will generate vapours which may form explosive vapour/air mixtures. Avoid heat, flames and other sources of ignition. Avoid excessive heat prolonged periods of time. May polymerise. Avoid contact with oxidisers or reducing agents. Bases, alkalies (inorganic). Bases, alkalies (organic). Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11. TOXICOLOGICAL INFORMATION Methyl methacrylate LD50/oral/rat 7872 mg/kg LC50/in/4h/rat 7093 ppm Methacrylic acid LD50/oral/rat 1060 mg/kg LC50/inh/4h/rat - >2000 mg/kg Inhalation: Vapours have a narcotic effect and may cause headache, fatigue, dizziness and nausea. In high concentrations, vapours are anaesthetic and may cause headache,
4 Issuance date: Revision date: Page 4/7 Ingestion: Skin contact: Eye contact: Target organs: fatigue, dizziness and central nervous system effects. Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal tract. Irritating. May cause nausea, stomach pain and vomiting. May be absorbed through the skin. Irritating to skin. Prolonged and frequent contact may cause redness and irritation. May cause sensitisation by skin contact. Ris of sensitisation or allergic among sensitive individuals. Irritating to eyes. Risk of corneal damage. prolonged or repeated exposure may cause: may cause damage to the liver and kidneys. Respiratory system, lungs. Central nervous system. Prolonged or repeated inhalation may cause: asthma-like shortness of breath. 12. ECOLOGICAL INFORMATION Ecotoxicity: Mobility: Avoid release to the environment. Bioaccumulation. Do not contaminate water. Degradability: Methyl methacrylate monomer: biochemical oxygen demand within 5 days (BOD5) = 14 g/g 0,9 g/g Water hazard classification: WKG DISPOSAL CONSIDERATIONS Disposal methods: Dispose of waste and residues in accordance with local authority requirements. Waste class TRANSPORT INFORMATION ADR/RID Proper shipping name Adhesives Unno ADR Class 3 ADR Pack group Class 3: Flammable liquids Hazard no. : 33 Label no.: 3 Hazchem code : 3YE CEFIC Tec(r) no. 30GF-I+, 30GF1-sp RID Class 3 RID Pack group IMDG Proper shipping name Adhesives UN no Class 3 Pack group EmS F-E, S-D MFAG See Guide Marine pollutant No. IATA
5 Revision date: Page 5/7 Proper shipping name Adhesives UN no IACO Class 3 Pack group 15. REGULATORY INFORMATION The products has been classified and marked in accordance wth EU directives /Ordinance and Hazardous Materials. National regulations: Dyrektywa Komisji 2001/58/WE dotycząca kart charakterystyki; Dyrektywa Komisji 2006/8/WE z dnia 23 stycznia 2006 r dotycząca klasyfikacji, pakowania i etykietowania preparatów niebezpiecznych; Dyrektywa Komisji 2001/59/WE dotycząca klasyfikacji, opakowania i oznakowania niebezpiecznych substancji - 28 dostosowanie; Dyrektywa Parlamentu i Rady 1999/45/WE i 2001/60/WE dotycząca niebezpiecznych preparatów; Dyrektywa Rady 1999/13/WE z 11 marca 1999 o limitach dla emisji lotnych związków organicznych wynikających z użytkowania rozpuszczalników organicznych podczas określonych prac i na określonych instalacjach Dyrektywa Parlamentu Europejskiego i Rady 2003/105/WE z dnia 16 grudnia 2003 r., zmieniającej dyrektywę Rady 96/82/WE (Seveso ) w sprawie kontroli nie bezpieczeństwa poważnych awarii związanych z substancjami niebezpiecznymi Rozporządzenie (WE) nr 1907 Parlamentu Europejskiego i Rady z dnia 18 grudnia 2006 w sprawie rejestracji, oceny, udzielania zezwoleń i stosowanych ograniczeń w zakresie chemikaliów (REACH) Rozporządzenie Ministra Zdrowia z dnia 2 września 2003 r. w sprawie kryteriów i sposobu klasyfikacji substancji i preparatów chemicznych (Dz. U. 2003r. nr.171, poz.1666, poz. 1679), z późniejszymi zmianami. Ustawa z dnia 11 stycznia 2001 roku o substancjach i preparatach chemicznych wraz z późniejszymi zmianami (Dz.U. 2001r. nr 142, poz.1187) Rozporządzenie Ministra Pracy i Polityki Socjalnej z 29 listopada 2002 w sprawie najwyższych dopuszczalnych stężeń i natężeń czynników szkodliwych dla zdrowia w środowisku pracy (Dz.U. 2002r. nr 217 z poz z późniejszymi zmianami) Rozporządzenie Ministra Zdrowia z dnia 20 kwietnia 2005 roku w sprawie badań i pomiarów czynników szkodliwych dla zdrowia w środowisku pracy (Dz.U. 2005r. nr 73, poz. 645) Rozporządzenie Ministra Zdrowia z dnia 21 grudnia 2005 roku w sprawie zasadniczych wymagań dla środków ochrony indywidualnej (Dz.U. 2005r. nr 259 poz. 2173) Ustawa z dnia 11 stycznia 2001 roku o substancjach i preparatach chemicznych (Dz.U. 2001r. nr 11 pozycja 84 z późniejszymi zmianami) Rozporządzenie Ministra Zdrowia z dnia 5 marca 2009 roku w sprawie oznakowania opakowań substancji niebezpiecznych i preparatów niebezpiecznych oraz niektórych preparatów chemicznych (Dz. U. 2009r nr 59 poz.439) Rozporządzenie Ministra Zdrowia z dnia 14 października 2005 roku w sprawie wykazu substancji niebezpiecznych wraz z ich klasyfikacją i oznakowaniem (Dz.U. 2005r. nr 201 poz 1674 z późniejszymi zmianami) Rozporządzenie Ministra Zdrowia z dnia 30 kwietnia 2004 roku w sprawie substancji niebezpiecznych i preparatów niebezpiecznych, których opakowania zaopatruje się w zamknięcia utrudniające dostęp przez dzieci i wyczuwalne dotykiem ostrzeżenie o niebezpieczeństwie (Dz.U. 2004r. nr 128 poz. 1348) Ustawa z dnia 27 kwietnia 2001 roku o odpadach (Dz.U. 2001r. nr 62 poz. 628 z późniejszymi zmianami). Rozporządzenie Ministra Środowiska z dnia 27 września 2001 roku w sprawie katalogu odpadów (Dz.U. 2001r. nr 112 poz. 1206) Ustawa z dnia 11 maja 2001 roku o opakowaniach i odpadach opakowaniowych (Dz.U. 2001r. nr 63 poz 638 z późniejszymi zmianami). Rozporządzenia Ministra Środowiska z dnia 29 listopada 2002 r.(dz. U. Nr 212, poz. 1799) w sprawie warunków, jakie należy spełniać przy wprowadzaniu ścieków do wód lub do ziemi oraz w sprawie substancji szczególnie szkodliwych dla środowiska wodnego. Umowa Europejska dotycząca międzynarodowego przewozu drogowego towarów niebezpiecznych ADR (obowiązująca od ) (Dz.U. 2005r. nr 178 poz. 1481) Ustawa z dnia 28 października 2002 roku o przewozie drogowym towarów niebezpiecznych (Dz.U. nr 199 poz 1671 z późniejszymi zmianami) Rozporządzenie Ministra Zdrowia z dnia 13 listopada 2007 roku w sprawie karty charakterystyki (Dz.U. nr 215 poz. 1588)
6 Issuance date: Revision date: Page 6/7 Rozporządzenie Ministra Zdrowia z dnia 17 stycznia 2003 roku w sprawie informacji o preparatach niebezpiecznych, dla których nie jest wymagane dostarczenie karty charakterystyki (Dz.U. 2003r. nr 19 poz 170) Rozporządzenie Ministra Zdrowia z dnia 13 stycznia 2004 roku w sprawie substancji chemicznych występujących w produkcji lub w obrocie, podlegających zgłoszeniu (Dz.U nr 12 poz 111) Rozporządzenie Ministra Gospodarki i Pracy z dnia 5 lipca 2004 roku w sprawie ograniczeń, zakazów lub warunków produkcji, obrotu lub stosowania substancji niebezpiecznych i preparatów niebezpiecznych oraz zawierających je produktów (Dz.U. 2004r. nr 168 poz z późniejszymi zmianami) Rozporządzenie Ministra Zdrowia z dnia 30 grudnia 2004 roku w sprawie bezpieczeństwa i higieny pracy związanej z występowaniem w miejscy pracy czynników chemicznych (Dz.U nr 11 poz 86) Rozporządzenie Ministra Zdrowia z dnia 1 grudnia 2004 w sprawie substancji, preparatów, czynników lub procesów technologicznych o działaniu rakotwórczym lub mutagennym w środowisku pracy (Dz.U nr 280 poz.2771 z późniejszymi zmianami) Rozporządzenie MPiPS z dnia 18 grudnia 2002r w sprawie dopuszczalnych stężeń i natężeń czynników szkodliwych dla zdrowia w środowisku pracy (Dz.U. 2002r Nr 217, poz z późniejszymi zmianami) Labelling: C Corrosive F Highly flammable Contains: Methacrylic acid, methyl methacrylate Risk phrases: R34 R43 R36/37/38 Causes burns May cause sensitization by skin contact Irritating to eyes, to respiratory system and skin Safety phrases: S1 Keep locked up S2 Keep out of the reach of children S9 Keep container in a well-ventilated place S16 Keep away from sources of ignition - No smoking S24/25 Avoid contact with skin and eyes S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S27 Take off immediately all contaminated clothing S29 Do not empty into drains S33 Take precautionary measures against static discharges S36/37/39 Wear suitable protective clothing, gloves and eye/face protection S51 Use only in well-ventilated areas 16. OTHER INFORMATION The rest phrases: Xn Xi Harmful Irritant
7 Revision date: Page 7/7 Full R-phrases: R11 Highly flammable R34 Causes burns R35 Causes severe burns R43 May cause sensitisation by skin contact R36/37/38 Irritating to eyes, respiratory system and skin R37/38 Irritating to respiratory system and skin R21/22 Harmful in contact with skin and if swallowed Revision: 1. Issuance date: Revision date: Modification of itmes: 8, 12, 15, 16 This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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